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KMID : 1059519850290050478
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Journal of the Korean Chemical Society
1985 Volume.29 No. 5 p.478 ~ p.481
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Kinetic Studies on Nucleophilic Substitution Reactions of Alkane Sulfonylchlorides with Anilines in MeOH-MeCN Mixtures
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Lee Ik-Choon
Kang Han-Keun
Lee Hai-Whang
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Abstract
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Nucleophilic substitution reactions between Alkanesulfonylchlorides and p-substituted anilines in methanol-acetonitrile mixture have been studied kinetically. Reactivities of substrates, substituent effects of nucleophile and solvent effects indicate that the studied reaction proceeds via $S_N2$. The kinetic results show that transition state of the reaction between i-PSC and anilines becomes looser as the composition of methanol increases.
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